Vinylcyclopropane Oxygenation. Anti Diastereoselectivity through an Unexpected Transition-State Geometry

DOI: 10.1021/jo00043a007

Source and publish data:

Journal of Organic Chemistry p. 4574 - 4576 (1992)

Update date:2022-08-04

Topics:

Authors:

Feldman, Ken S.

Kraebel, Carolyn M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00043a007

Ester-substituted vinylcyclopropanes react with molecular oxygen via a radical-mediated <3-atom + 2-atom> addition to form 1,2-dioxolanes with predominantly anti stereochemistry.The degree of anti stereoselectivity can be controlled by the electronic natu

Full text of DOI:10.1021/jo00043a007

Products guided by the article

Product name:(3R,5S)-5-Vinyl-[1,2]dioxolane-3-carboxylic acid pentafluorophenyl ester

Cas No:143171-15-7

R&D Labs maybe for 143171-15-7

Jiaxing Carry Bio-Chem Technology Co.,Ltd

website:http://www.carrybiotech.com

Contact:0573-82788958

Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China
Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Changzhou Litong Chemical Co., Ltd.

website:http://www.litonchem.com/

Contact:+86-519-86301238

Address:Laoba Rd, Hutang town Changzhou Jiangsu
Jiaxing Anrui Material Technology Co., Ltd.

Contact:86-573-82651652 13305832579

Address:Room 407, Technology Building, 1369 Chennan Road, Jiaxing City, Zhejiang, China
JIANGXI XINXIN CHEMICAL CO., LTD.

Contact:86-15957176628

Address:INDUSTRY ROAD 1, INDUSTRIAL PARK, HEKOU TOWN,YANSHAN COUNTY, JIANGXI PROVINCE, CHINA

Relevant to this article

Fragmentation Selectivity in Electron Impact Ionization Mass Spectra of Substituted Dimethoxybenzenes

Doi:10.1002/oms.1210270613
(1992)
Induction of motion in a synthetic molecular machine: Effect of tuning the driving force

Doi:10.1002/chem.201204016
(2013)
Photochemistry of Nucleoside Transport Inhibitor 6-S-Benzylated Thiopurine Ribonucleosides. Implications for a New Class of Photoaffinity Labels

Doi:10.1021/jo00048a034
(1992)
Coordinative Cocatalysis via In³⁺. A Chemoselectivity Switch for Pd-Catalyzed Cycloadditions

Doi:10.1021/ja00046a041
(1992)
Synthesis of aromatic α-aminoesters: Palladium-catalyzed long-range arylation of primary C_sp3-H bonds

Doi:10.1002/anie.201206237
(2012)
Controlling the structural and electrical properties of diacid oligo(phenylene ethynylene) langmuir-blodgett films

Doi:10.1002/chem.201203261
(2013)

Article Doi