Lewis Acid Promoted Stereoselective Carbon-Carbon Bond Formation of 3-Formyl-Δ2-isoxazolines

DOI: 10.1021/jo00046a023

Source and publish data:

Journal of Organic Chemistry p. 5403 - 5413 (1992)

Update date:2022-08-04

Topics:

Authors:

Kamimura, Akio

Yoshihara, Kosei

Marumo, Shinji

Yamamoto, Akinori

Nishiguchi, Takeshi

et al. et al.

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Article abstract of DOI:10.1021/jo00046a023

4,5-Disubstituted 3-formyl-Δ²-isoxazolines undergo the aldol, allylation, and carbonyl ene reactions in the presence of appropriate Lewis acid to give the adducts with an effective 1,3-asymmetric induction.The stereoselectivity of the reaction

Full text of DOI:10.1021/jo00046a023

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Product name:3-(tert-Butyl-dimethyl-silanyloxy)-3-((4S,5S)-4,5-diphenyl-4,5-dihydro-isoxazol-3-yl)-propionaldehyde

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