Metalated nitriles: N- and C-coordination preferences of Li, Mg, and Cu cations

DOI: 10.1039/c3cc41703d

Source and publish data:

Chemical Communications p. 4700 - 4702 (2013)

Update date:2022-09-26

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Authors:

Purzycki, Matthew

Liu, Wang

Hilmersson, Goeran

Fleming, Fraser F.

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Article abstract of DOI:10.1039/c3cc41703d

¹³C NMR analyses of a series of metalated arylacetonitriles and cyclohexanecarbonitriles with the synthetically relevant metals Li, Mg, and Cu identifies the influence of the carbon scaffold and the nature of the metal on the preference for N- or C-metalation. The Royal Society of Chemistry 2013.

Full text of DOI:10.1039/c3cc41703d

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