SYNTHESIS OF cis-DECALIN DERIVATIVE VIA ?-ALLYLPALLADIUM INTERMEDIATE AND ITS TRANSFORMATION TO USEFULLY FUNCTIONALIZED trans-DECALINE DERIVATIVE

DOI: 10.1016/S0040-4039(00)92680-7

Source and publish data:

Tetrahedron Letters p. 3527 - 3530 (1992)

Update date:2022-08-05

Topics:

Authors:

Takemoto, Toshiyasu

Nishikimi, Yuji

Sodeoka, Mikiko

Shibasaki, Masakatsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)92680-7

Treatment of 15 or 16 with Pd(PPh3)4 (10 mol percent) and NaH (1.2 equiv) afforded the cis-decalin derivative 18 stereoselectively in high yield, which was effectively transformed into the usefully functionalized trans-decalin derivative 29.

Full text of DOI:10.1016/S0040-4039(00)92680-7

Products guided by the article

Product name:1-(4-Methoxycarbonyl-3-oxo-butyl)-cyclohexa-2,5-dienecarboxylic acid methyl ester

Cas No:143406-45-5

R&D Labs maybe for 143406-45-5

Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Wuhan Soleado Technology Co.,Ltd.

Contact:86-2783341481 18971291927

Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
Tianjin Bright Future Technology Co., Ltd

Contact:0086-22-58016666

Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China
ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei
HANGZHOU YUNUO CHEMICAL CO.,LTD

website:http://www.yunuochem.com

Contact:0571-83715115

Address:hangzhou

Relevant to this article

Discovery of potent transient receptor potential vanilloid 1 antagonists: Design and synthesis of phenoxyacetamide derivatives

Doi:10.1016/j.bmcl.2013.04.016
(2013)
Ultrasound-promoted, rapid and green synthesis of phosphonamide derivatives under catalyst and solvent-free conditions

Doi:10.1080/10426507.2020.1854254
(2020)
Aminoethylation. II. Reactions of meso cis cyclohexenimine and its derivative with diethyl malonate. Synthesis of trans octahydroindole (Japanese)

Doi:10.1248/yakushi1947.95.7_889
(1975)
Novel hybrids of (phenylsulfonyl)furoxan and anilinopyrimidine as potent and selective epidermal growth factor receptor inhibitors for intervention of non-small-cell lung cancer

Doi:10.1021/jm400463q
(2013)
Dihalocyclopropanation of phenylthio or butylthiocycloalkenes under phase transfer conditions. Opening of cyclopropanes under microwave irradiation

Doi:10.1080/00397919208021338
(1992)
Efficient remote axial-to-central chirality transfer in enantioselective SmI₂-mediated reductive coupling of aldehydes with crotonates of atropisomeric 1-naphthamides

Doi:10.1021/jo0526486
(2006)

Article Doi