SYNTHESIS OF cis-DECALIN DERIVATIVE VIA ?-ALLYLPALLADIUM INTERMEDIATE AND ITS TRANSFORMATION TO USEFULLY FUNCTIONALIZED trans-DECALINE DERIVATIVE

DOI: 10.1016/S0040-4039(00)92680-7

Source and publish data:

Tetrahedron Letters p. 3527 - 3530 (1992)

Update date:2022-08-05

Topics:

Authors:

Takemoto, Toshiyasu

Nishikimi, Yuji

Sodeoka, Mikiko

Shibasaki, Masakatsu

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Article abstract of DOI:10.1016/S0040-4039(00)92680-7

Treatment of 15 or 16 with Pd(PPh3)4 (10 mol percent) and NaH (1.2 equiv) afforded the cis-decalin derivative 18 stereoselectively in high yield, which was effectively transformed into the usefully functionalized trans-decalin derivative 29.

Full text of DOI:10.1016/S0040-4039(00)92680-7

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