SYNTHESIS OF cis-DECALIN DERIVATIVE VIA ?-ALLYLPALLADIUM INTERMEDIATE AND ITS TRANSFORMATION TO USEFULLY FUNCTIONALIZED trans-DECALINE DERIVATIVE

DOI: 10.1016/S0040-4039(00)92680-7

Source and publish data:

Tetrahedron Letters p. 3527 - 3530 (1992)

Update date:2022-08-05

Topics:

Authors:

Takemoto, Toshiyasu

Nishikimi, Yuji

Sodeoka, Mikiko

Shibasaki, Masakatsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)92680-7

Treatment of 15 or 16 with Pd(PPh3)4 (10 mol percent) and NaH (1.2 equiv) afforded the cis-decalin derivative 18 stereoselectively in high yield, which was effectively transformed into the usefully functionalized trans-decalin derivative 29.

Full text of DOI:10.1016/S0040-4039(00)92680-7

Products guided by the article

Product name:1-(4-Methoxycarbonyl-3-oxo-butyl)-cyclohexa-2,5-dienecarboxylic acid methyl ester

Cas No:143406-45-5

R&D Labs maybe for 143406-45-5

Jinhua Haoyuan Chemical CO., LTD(expird)

Contact:86-579-82465583

Address:Jinhua,Zhejiang
Haitong Chemical Industrial Co.,Ltd.

website:https://www.haitonglongwin.com/

Contact:+86-022-66221018

Address:18-701, No.99, The 4th Street, TEDA,
Shijiazhuang Sdyano Fine Chemical Co., Ltd

Contact:+86-311-89830448

Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)

Contact:+86-571-87046953

Address:No. 37, Qingchun Road
NIGNXIA XINDACHANG TECHNOLOGY CO.,LTD

Contact:86-0951-7815345

Address:North side of Qiyuan Road, west side of Yuanfeng Highway, New Material Park, Ningdong Energy and Chemical Industry Base, Ningxia,China

Relevant to this article

Discovery of potent transient receptor potential vanilloid 1 antagonists: Design and synthesis of phenoxyacetamide derivatives

Doi:10.1016/j.bmcl.2013.04.016
(2013)
Ultrasound-promoted, rapid and green synthesis of phosphonamide derivatives under catalyst and solvent-free conditions

Doi:10.1080/10426507.2020.1854254
(2020)
Aminoethylation. II. Reactions of meso cis cyclohexenimine and its derivative with diethyl malonate. Synthesis of trans octahydroindole (Japanese)

Doi:10.1248/yakushi1947.95.7_889
(1975)
Novel hybrids of (phenylsulfonyl)furoxan and anilinopyrimidine as potent and selective epidermal growth factor receptor inhibitors for intervention of non-small-cell lung cancer

Doi:10.1021/jm400463q
(2013)
Dihalocyclopropanation of phenylthio or butylthiocycloalkenes under phase transfer conditions. Opening of cyclopropanes under microwave irradiation

Doi:10.1080/00397919208021338
(1992)
Efficient remote axial-to-central chirality transfer in enantioselective SmI₂-mediated reductive coupling of aldehydes with crotonates of atropisomeric 1-naphthamides

Doi:10.1021/jo0526486
(2006)

Article Doi