NICKEL(0)-INDUZIERTE C-C-VERKNUEPFUNG ZWISCHEN 1,2-DIENEN UND KOHLENDIOXID

Article abstract of DOI:10.1016/0022-328X(84)80145-X

1,2-Dienes react with CO2 at nickel(0) under the influence of basic chelate ligands to form nickela carboxylates.The structures of these five-membered complexes have been determined by spectroscopic and chemical methods.The regioselectivity of the C-C bond formation is discussed.