Radical mediated enantioselective construction of C-1 to C-9 segment of rhizoxin

DOI: 10.1016/S0040-4039(00)74816-7

Source and publish data:

Tetrahedron Letters p. 3907 - 3910 (1992)

Update date:2022-08-04

Topics:

Authors:

Rama Rao

Sharma Sharma

Bhanu, Manjunath N.

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Article abstract of DOI:10.1016/S0040-4039(00)74816-7

A highly enantioselective route has been devised for the synthesis of the 3,5 cis-disubstituted valerolactone moiety (C-1 to C-9 segment) of rhizoxin via intramolecular radical cyclisation of suitably functionalised 6-heptenyl radical.

Full text of DOI:10.1016/S0040-4039(00)74816-7

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