Stereoselective Michael additions of titanium "ate" complexes of ketone and ester enolates

DOI: 10.1016/0040-4020(92)80010-D

Source and publish data:

Tetrahedron p. 5597 - 5606 (1992)

Update date:2022-08-04

Topics:

Authors:

Bernardi, Anna

Dotti, Pierfranco

Poli, Giovanni

Scolastico, Carlo

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Article abstract of DOI:10.1016/0040-4020(92)80010-D

The conjugate addition of Ti "ate" complexes of ketone and ester enolates to α,β-unsaturated carbonyl compounds was studied. The reaction was found to be highly regio- and stereoselective. Compared to the lithium enolates, ketone enolate Ti complexes show

Full text of DOI:10.1016/0040-4020(92)80010-D

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