Angewandte Chemie - International Edition p. 9791 - 9795 (2013)
Update date:2022-08-04
Topics:
Deb, Mohit L.
Dey, Suvendu S.
Bento, Isabel
Barros, M. Teresa
Maycock, Christopher D.
Traffic control: The hydroxy functional group directs the α-functionalization of tertiary amines, synthesizing 1,3-oxazines by C-O bond formation. Reaction occurs with both benzylic and non-benzylic amines. In the case of naphthoxazine synthesis, 100 % diastereoselectivity was observed. A tentative two-pathway mechanism is proposed for the reaction. Copyright
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