Preparation of alkyl-substituted indoles in the benzene portion. Part 11. Total synthesis of (6R,8S)-herbindole A, (6R,8S)-herbindole B, (6R,8S)-herbindole C (6R,8S)-cis-trikentrin A, (6R,8S)-cis-trikentrin B, (6R,8R)-trans-trikentrin B, and (6R,8R)-iso-t

DOI: 10.1248/cpb.42.854

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Chemical and Pharmaceutical Bulletin p. 854 - 864 (1994)

Update date:2022-08-03

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Authors:

Muratake

Mikawa Mikawa

Seino Seino

Natsume Natsume

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Article abstract of DOI:10.1248/cpb.42.854

The key intermediate, (3R,5S)-3,5-dimethyl-1-cyclopentenylmethanol (13) for chiral syntheses of herbindoles and trikentrins, was prepared from the known Diels-Alder adduct 12. Employing pertinent methodologies developed in the previous model study (preced

Full text of DOI:10.1248/cpb.42.854

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