Synthesis p. 787 - 792 (1992)
Update date:2022-08-02
Topics:
Bestmann
Bomhard
Dostalek
Pichl
Riemer
Zimmermann
Alkylidenetriphenylphosphoranes 1 react with trialkyl halosilanes 2 to afford silylated alkylidenephosphoranes 5, which can be converted to acylated alkylidenephosphoranes 8 and 10 by trimethylsilyl carboxylates 6 or carboxylic anhydrides 10. Bis(acylalkylidenephosphoranes) 13-15 are available from 5 and bis(trimethylsilyl) dicarboxylates 12 or cyclic or polymeric anhydrides 16, 17.
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Doi:10.1002/adsc.201900097
(2019)Doi:10.1021/jm970636+
(1998)Doi:10.1021/jo400580n
(2013)Doi:10.1016/j.bmc.2016.08.029
(2016)Doi:10.1016/j.tet.2013.02.091
(2013)Doi:10.1080/00397919208021642
(1992)
