Stereoselection in Thermal Asymmetric Diels-Alder Reactions. Electronic vs Steric Effects

DOI: 10.1021/jo00050a037

Source and publish data:

Journal of Organic Chemistry p. 6566 - 6575 (1992)

Update date:2022-08-04

Topics:

Authors:

Stammen, Blanda

Berlage, Ulrich

Kindermann, Richard

Kaiser, Manfred

Guenther, Barbara

et al. et al.

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Article abstract of DOI:10.1021/jo00050a037

Experimental evidence was found for an electronic contribution favoring the cisoid conformation of α,β-unsaturated carbonyl compounds in thermal Diels-Alder transition states.

Full text of DOI:10.1021/jo00050a037

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