Stereoselection in Thermal Asymmetric Diels-Alder Reactions. Electronic vs Steric Effects

DOI: 10.1021/jo00050a037

Source and publish data:

Journal of Organic Chemistry p. 6566 - 6575 (1992)

Update date:2022-08-04

Topics:

Authors:

Stammen, Blanda

Berlage, Ulrich

Kindermann, Richard

Kaiser, Manfred

Guenther, Barbara

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00050a037

Experimental evidence was found for an electronic contribution favoring the cisoid conformation of α,β-unsaturated carbonyl compounds in thermal Diels-Alder transition states.

Full text of DOI:10.1021/jo00050a037

Products guided by the article

Product name:(2S)-2-hydroxy-1-(1-methylbicyclo<2.2.1>hept-5-en-2-yl)propan-1-one

Cas No:144193-75-9

R&D Labs maybe for 144193-75-9

Chengdu Baishixing Science and Technology Industry Co., Ltd.

website:http://www.cd-bsx.com

Contact:+86-28-88531548

Address:#217,North of Industry Road,Heshan Town,Pujiang County,Chengdu,Sichuan,China.
SJZ Chenghui Chemical Co., Ltd.

Contact:86-311-87713916

Address:no.368 youyi north avenue
HANGZHOU FOREWIN PHARMA CO., LTD

Contact:+86-571-89053961

Address:hangzhou
Improve Medical Technology(Nanxiong) Co., Ltd

Contact:86-751-3836997

Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China
Penglai Qianwei Chemical Co., Ltd.

Contact:86-535-3357802

Address:Shahelu (north), Penglai, Shandong, China

Relevant to this article

Preparation of the zinc enolate equivalent of amides by zinciomethylation of isocyanates: Catalytic asymmetric Reformatsky-type reaction

Doi:10.1055/s-0034-1378514
(2014)
Synthesis and characterization of novel gold(III) complexes with polydentate N-donor ligands based on the pyridine and triazole heterocycles

Doi:10.1016/j.inoche.2013.04.015
(2013)
Decoration of gold nanoparticles by a double-armed calix[4]pyrrole: A receptor-decorated nanoensemble for anion sensing and extraction

Doi:10.1002/chem.201300472
(2013)
Compositional Variation of Ionizable Crown Ether-Alkali Metal Ion Complexes in the Solvent Extraction Using Several Extraction Solvents

Doi:10.1246/cl.1992.1535
(1992)
Condensation of amino derivatives of benzimidazol-2-ones and imidazo[4,5-b]pyridin-2-ones with 2,6-dimethyl-γ-pyrone in acetic acid

Doi:10.1134/S107042801305031X
()
Ultrasound-Promoted Three-Component Reaction of N -isocyaniminotriphenyl-phosphorane, (E)-cinnamic Acids, and Biacetyl

Doi:10.1080/10426507.2014.909428
(2015)

Article Doi