Bulletin of the Chemical Society of Japan p. 2272 - 2274 (1992)
Update date:2022-07-30
Topics:
Kita, Masakazu
Yamamoto, Takashi
Kashiwabara, Kazuo
Fujita, Junnosuke
Bis<2-(dimethylphosphino)ethane-1-thiolato> complexes of Ni(II), Pd(II), and Pt(II) were newly prepared, and the molecular structure of the Ni(II) complex was determined by X-ray analysis to have a square planar trans(P,P) geometrical configuration.The 1H, 13C, and 31P NMR spectra of the complexes in CDCl3 indicate a trans(P,P) structure for the nickel(II) and palladium(II) complexes and a cis(P,P) one for the platinum(II) complex.
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Doi:10.1021/jm400233w
(2013)Doi:10.1246/cl.2003.1036
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(2013)
