Use of Molecular Sieves for Promotion of Diastereoselectivity in Palladium-catalysed Oxidative Cyclisation. Reversal of Diastereofacial Selectivity

DOI: 10.1039/c39910000218

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 218 - 220 (1991)

Update date:2022-08-05

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Authors:

Heumann, Andreas

Tottie, Louise

Moberg, Christina

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Article abstract of DOI:10.1039/c39910000218

Molecular sieves have a decisive influence on the oxidative cyclisation of cis-1,2-divinylcyclohexane, resulting in enhanced diastereoselectivity (17-62percent) as well as, occasionally, in opposite absolute configuration of the newly created chiral centres.

Full text of DOI:10.1039/c39910000218

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