
Tetrahedron Letters p. 5827 - 5830 (1992)
Update date:2022-07-30
Topics:
Zhou
Huang
Shi
Trimethylsilylated diisobutyltelluronium allylide, a moderately stabilized telluronium ylide, generated from 3-trimethylsilyl-2-propenyldiisobutyltelluronium bromide (3) with LiTMP, reacted with carbonyl compounds to afford trimethylsilylvinyl oxiranes in excellent yields with high syn stereoselectivity.
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(1992)