A convenient and stereoselective synthesis of trimethylsilylvinyl oxiranes via silylated telluronium allylide+

DOI: 10.1016/0040-4039(92)89042-B

Source and publish data:

Tetrahedron Letters p. 5827 - 5830 (1992)

Update date:2022-07-30

Topics:

Authors:

Zhou Zhou

Huang Huang

Shi Shi

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Article abstract of DOI:10.1016/0040-4039(92)89042-B

Trimethylsilylated diisobutyltelluronium allylide, a moderately stabilized telluronium ylide, generated from 3-trimethylsilyl-2-propenyldiisobutyltelluronium bromide (3) with LiTMP, reacted with carbonyl compounds to afford trimethylsilylvinyl oxiranes in excellent yields with high syn stereoselectivity.

Full text of DOI:10.1016/0040-4039(92)89042-B

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