A convenient and stereoselective synthesis of trimethylsilylvinyl oxiranes via silylated telluronium allylide+

DOI: 10.1016/0040-4039(92)89042-B

Source and publish data:

Tetrahedron Letters p. 5827 - 5830 (1992)

Update date:2022-07-30

Topics:

Authors:

Zhou Zhou

Huang Huang

Shi Shi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(92)89042-B

Trimethylsilylated diisobutyltelluronium allylide, a moderately stabilized telluronium ylide, generated from 3-trimethylsilyl-2-propenyldiisobutyltelluronium bromide (3) with LiTMP, reacted with carbonyl compounds to afford trimethylsilylvinyl oxiranes in excellent yields with high syn stereoselectivity.

Full text of DOI:10.1016/0040-4039(92)89042-B

Products guided by the article

Product name:Silane, [2-(3,3-diphenyloxiranyl)ethenyl]trimethyl-, (E)-

Cas No:144512-14-1

R&D Labs maybe for 144512-14-1

SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
NINGBO PANGS CHEM INT’L CO., LTD.

Contact:+86-0574-27666801

Address:Floor 21, Building 11, Xintiandi, No. 689, Shijiroad, Ningbo, Zhejiang, China
Suzhou HeChuang Chemical Co.,Ltd.

Contact:+86-512-88800520

Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu

Relevant to this article

Switching of the triplet excited state of the C₆₀-dimethylaminostyryl BODIPY dyads/triads

Doi:10.1039/c4tc02037e
(2015)
A VERSATILE ROUTE TO MIXED VINYLKETENE ACETALS : USE OF 1-t-BUTYLDIMETHYLSILOXY-1-ETHOXY BUTADIENE IN CYCLOHEXENONE SYNTHESIS

Doi:10.1016/S0040-4039(01)80823-6
(1985)
Synthesis and thin-film transistor performance of benzodipyrrolinone and bithiophene donor-acceptor copolymers

Doi:10.1039/c2jm34867e
(2012)
Benzo[1,2-b:4,5-b']dithiophene as a weak donor component for push-pull materials displaying thermally activated delayed fluorescence or room temperature phosphorescence

Doi:10.1016/j.dyepig.2020.109022
(2021)
A structural study of DPP-based sensitizers for DSC applications

Doi:10.1039/c2cc35125k
(2012)
Lossen-like Rearrangement of N-<α-Methylbenzyl(phenyl)phosphinoyl>-O-methylsulfonylhydroxylamine with Methylamine: Retention of Configuration at Phosphorus as revealed by X-Ray Crystallography

Doi:10.1039/c39920000227
(1992)

Article Doi