Chemistry - A European Journal p. 17698 - 17701 (2013)
Update date:2022-08-04
Topics:
Chausset-Boissarie, Laetitia
Ghozati, Kazem
Labine, Emily
Chen, Jack L.-Y.
Aggarwal, Varinder K.
Crudden, Cathleen M.
An original syn: The first enantioselective Suzuki-Miyaura cross-coupling of chiral, enantioenriched secondary allylic boronic esters is described (see scheme; DME=dimethoxyethane, Bpin = pinacolboryl, dba = dibenzylideneacetone). Mechanistic studies show that the reactions proceed via γ-selective transmetalation followed by reductive elimination. The reaction provides the first independent confirmation that the transmetalation of boronic esters proceeds via a syn pathway. Copyright
View MoreArshine Pharmaceutical Co., Limited
website:http://www.cnarshine.com
Contact:0731-88503671
Address:Room 1109.Block C3, Lugu Enterprise Plaza,No.27 Wenxuan Road,Changsha National Hi-Tech Industrial Development Zone,Hunan ,P.R.China
Shenyang Xingzhenghe Chemical Co., Ltd.
Contact:024-23509232
Address:No. 33, Naner Road, Heping Dist.
Tangshan Wisdom Trading Co.,Ltd
Contact:86 315 2222979
Address:No.41 BeiXinXi Road, Yangguang building 1-1102 , Tangshan, Hebei, China
Shanghai Massive Chemical Technology Co., Ltd.
website:http://www.massivechem.com/
Contact:+86 21 34943721
Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
Contact:+86-22-26358246
Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Doi:10.1021/jm00024a008
(1995)Doi:10.1016/j.saa.2013.04.045
(2013)Doi:10.1016/S0040-4039(00)79089-7
(1992)Doi:10.1055/s-0032-1316897
(2013)Doi:10.1016/S0040-4020(01)80456-7
(1992)Doi:10.1039/c3cc42423e
(2013)