Chemistry - A European Journal p. 17698 - 17701 (2013)
Update date:2022-08-04
Topics:
Chausset-Boissarie, Laetitia
Ghozati, Kazem
Labine, Emily
Chen, Jack L.-Y.
Aggarwal, Varinder K.
Crudden, Cathleen M.
An original syn: The first enantioselective Suzuki-Miyaura cross-coupling of chiral, enantioenriched secondary allylic boronic esters is described (see scheme; DME=dimethoxyethane, Bpin = pinacolboryl, dba = dibenzylideneacetone). Mechanistic studies show that the reactions proceed via γ-selective transmetalation followed by reductive elimination. The reaction provides the first independent confirmation that the transmetalation of boronic esters proceeds via a syn pathway. Copyright
View Morezhangjiagang bonded areas banggao co;ltd
website:http://www.shunchangchem.com
Contact:0086-13921972933
Address:Dongsha Chemical Zone.Zhangjiagang, Jiangsu Province
Contact:+86-134-5286-9121
Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
Ningbo Tide Imp. & Exp. Co., Ltd.
Contact:+86-571-8993 7933; +86-571-8993 6453
Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
Contact:+86-511-88790000
Address:338 North Yushan Rd, Zhenjiang, Jiangsu 212016
SuZhou Hua-Emy Chemical Import and Export Co., LTD.
Contact:+86-512-88804994; +86-512-88804550;
Address:710, Building B, International Trade Center, 12 Huanghelu, Changshu, Jiangsu,China
Doi:10.1021/jm00024a008
(1995)Doi:10.1016/j.saa.2013.04.045
(2013)Doi:10.1016/S0040-4039(00)79089-7
(1992)Doi:10.1055/s-0032-1316897
(2013)Doi:10.1016/S0040-4020(01)80456-7
(1992)Doi:10.1039/c3cc42423e
(2013)