SUPPRESSION OF RACEMIZATION DURING THE DIASTEREOSELECTIVE C-3 FUNCTIONALIZATION OF 5-HYDROXYMETHYL-2-PHENYLTHIO-(5H)-FURANONES

DOI: 10.1016/0040-4039(92)89006-X

Source and publish data:

Tetrahedron Letters p. 5689 - 5692 (1992)

Update date:2022-08-04

Topics:

Authors:

Wurster, Julie A.

Wilson, Lawrence J.

Morin, Gregory T.

Liotta, Dennis

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Article abstract of DOI:10.1016/0040-4039(92)89006-X

The methodology described herein examines the enantio- and stereoselective C-3 functionalization of 5-hydroxymethyl-2-(5H)-furanones via 1,4-organocuprate addition as well as the involvement of temperature and TMSCl in the selectivity.The results imply th

Full text of DOI:10.1016/0040-4039(92)89006-X

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