Organic Letters p. 3930 - 3933 (2013)
Update date:2022-08-05
Topics:
Pujari, Sandip A.
Guenee, Laure
Lacour, Jeroime
A direct nitrene insertion into C-N bonds is observed upon treatment of methano-Troeger bases with arylsulfonyl iminophenyliodinanes under copper and dirhodium catalysis. Novel cyclic imino-methano Troeger bases are obtained (55-88%). Enantiopure products (ee ≥ 99%) can be obtained with tailored substrates.
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Doi:10.1021/ol401862g
(2013)Doi:10.1002/anie.201708598
(2017)Doi:10.1002/ardp.19923250920
(1992)Doi:10.1016/j.tet.2013.05.131
(2013)Doi:10.1007/s00706-013-0934-6
(2013)Doi:10.1002/jlcr.3049
(2013)
