Studies on Diels-Alder reactions of 1,3,3-trimethyl-2-vinylcyclohexene with 2-cyclohexenones

DOI: 10.1016/S0040-4020(01)88309-5

Source and publish data:

Tetrahedron p. 9399 - 9416 (1992)

Update date:2022-09-26

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Authors:

Engler, Thomas A.

Sampath, UmaShanker

Velde, David Vander

Takusagawa, Fusao

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Article abstract of DOI:10.1016/S0040-4020(01)88309-5

The ZnBr₂-catalyzed reaction of 1,3,3-trimethyl-2-vinylcyclohexene (4) with 2-carbomethoxy-4,4-dimethyl-2-cyclohexenone at high pressure (12 kbar) produces the expected Diels-Alder product. However, reactions of (4) with the more sterically dem

Full text of DOI:10.1016/S0040-4020(01)88309-5

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