Unexpected Formation of an Inner Salt, Bis(N,N-diethylamino)carbeniumdithiocarboxylate, from 2-Chloro or 2-Phenoxy Substituted 1,1-Bis(N,N-diethylamino)ethylenes and Elemental Sulfur

DOI: 10.1039/c39920001522

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1522 (1992)

Update date:2022-08-04

Topics:

Authors:

Nakayama, Juzo

Akiyama, Isao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920001522

2-Chloro or 2-phenoxy substituted 1,1-bis(N,N-diethylamino)ethylenes 2a and c react with elemental sulfur in benzene at room temperature to give an inner salt, bis(N,N-diethylamino)carbeniumdithiocarboxylate 1a, in excellent yields.

Full text of DOI:10.1039/c39920001522

View Article Online / Journal Homepage / Table of Contents for this issue

Products guided by the article

Product name:2,2-bis(diethylamino)-2-ethylium-1-dithiocarboxylate

Cas No:145303-95-3

R&D Labs maybe for 145303-95-3

Suzhou Tianma Specialty Chemicals Co.,Ltd

Contact:+86-512-68090577

Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA
Changsha Goomoo Chemical Technology Co.Ltd

Contact:+86-731-82197655

Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
miao tie sheng

Contact:0311-13263231263

Address:jian hua street,Shijiazhuang City, China
Heliosense Biotechnologies, Inc.

website:https://www.heliosense.com/

Contact:+86-592-5667290

Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
Lonzeal Pharmaceuticals Co., Ltd.

website:http://www.lonzeal.com

Contact:+86-13381011962

Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China

Relevant to this article

Chemoselective Radiosyntheses of Electron-Rich [¹⁸F]Fluoroarenes from Aryl(2,4,6-trimethoxyphenyl)iodonium Tosylates

Doi:10.1021/acs.joc.9b00019
(2019)
The isoxazoline-5-spirocyclopropane route to (±)-Pumiliotoxin C

Doi:10.1016/S0040-4039(00)61023-7
(1992)
l-Proline catalyzed facile and efficient synthesis of functionalized indol-3-yl pyran derivatives by multi-component reactions

Doi:10.1007/s11164-017-2897-4
(2017)
Expedient Strategy for the Synthesis of 5-Acylethynylpyrrole-2-carbaldehydes

Doi:10.1080/00397911.2015.1034873
(2015)
Metal-free, ionic liquid-mediated synthesis of functionalized quinolines

Doi:10.1021/co500047w
(2014)
A novel strategy for targeting photodynamic therapy. Molecular combo of photodynamic agent zinc(II) phthalocyanine and small molecule target-based anticancer drug erlotinib

Doi:10.1039/c3cc45487h
(2013)

Article Doi