The use of bis(diphenylphosphinoacetylene) and its digold derivative as linking groups in osmium cluster chemistry. Crystal structures of 2(dppa)>, 2 and 2 (dppa = Ph2PCCPPh2>

DOI: 10.1016/0022-328X(92)83498-7

Source and publish data:

Journal of Organometallic Chemistry p. 219 - 231 (1992)

Update date:2022-07-31

Topics:

Authors:

Amoroso, Angelo J.

Johnson, Brian F.G.

Lewis, Jack

Massey, Anju D.

Raithby, Paul R.

Wong, Wing Tak

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Article abstract of DOI:10.1016/0022-328X(92)83498-7

The reaction of the activated triosmium cluster, with bis(diphenylphosphinoacetylene) (dppa) at room temperature affords the linked cluster <(Os3(CO)11>2(dppa)> (1), while the reaction of with an excess of dppa affords

Full text of DOI:10.1016/0022-328X(92)83498-7

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