Y(OTf)3 catalyzed substitution dependent oxidative C(sp 3)-C(sp3) cleavage and regioselective dehydration of β-allyl-β-hydroxydithioesters: Alternate route to α,β- unsaturated ketones and functionalized dienes

DOI: 10.1016/j.tet.2013.07.092

Source and publish data:

Tetrahedron p. 8899 - 8903 (2013)

Update date:2022-08-04

Topics:

Authors:

Chowdhury, Sushobhan

Chanda, Tanmoy

Nandi, Ganesh Chandra

Koley, Suvajit

Janaki Ramulu

Pandey Pandey

Singh, Maya Shankar

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/j.tet.2013.07.092

β-Allyl-β-hydroxydithioesters have been generated by the regioselective Grignard addition to the β-oxodithioesters. They have been successfully employed in selective C(sp³)-C(sp³) bond cleavage to construct α,β-unsaturated ketone res

Full text of DOI:10.1016/j.tet.2013.07.092

Products guided by the article

Product name:methyl 3-hydroxy-2-methyl-3-phenylhex-5-enedithioate

Cas No:1454846-20-8

R&D Labs maybe for 1454846-20-8

Hebei Fulong Import & Export Co., Ltd.

Contact:86-311-87795661

Address:15A19 Zhongyuan Building,368 Youyi North Street,Shijiazhuang 050070,China
jintan yufan Medicine Raw materials Co.,Ltd.(expird)

Contact:86-519-82808282

Address:6th,Jincheng Huangzhuang
Accendatech Co., LTD

Contact:+86-22-83718541

Address:32th Floor, Rongqiao Center Intersection of Changjiang Road and Nankai Six Road Nankai District Tianjin 300102, China
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Xian Lyphar Biotech Co., Ltd.

Contact:0086-29-89196322

Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China

Relevant to this article

Synthesis and fungicidal activities of 2-alkylthio-5-phenylmethylene-4h- imidazol-4-ones

Doi:10.1080/713744555
(2003)
Tricyclic 'oxadiazoaphosphorine oxide' guanosines: A new strategy to the protection of guanine bases during RNA synthesis

Doi:10.1016/S0040-4039(00)61764-1
(1992)
Total synthesis of attenols A and B

Doi:10.1016/j.tetlet.2013.08.043
(2013)
Singlet oxygen in synthesis. Oxazoles as carbonyl 1,1-dipole synthons

Doi:10.1016/S0040-4039(00)60874-2
(1992)
Catecholamine-protein conjugates: Isolation of an adduct of N-acetylhistidine to the side chain of N-acetyldopamine from an insect-enzyme catalyzed reaction

Doi:10.1016/S0040-4039(00)92150-6
(1991)
Diversity-oriented synthesis of spiro-oxindole-based 2,5-dihydropyrroles via three-component cycloadditions and evaluation on their cytotoxicity

Doi:10.1039/c3ra40874d
(2013)

Article Doi