Angewandte Chemie - International Edition p. 5691 - 5694 (2004)
Update date:2022-08-02
Topics:
Schneider, Christoph
Sreekanth, Anakallil R.
Mai, Enzo
A winning combination of metal and ligand: The catalyst formed in situ from Sc(OTf)3 and bipyridine 1 (10 mol%) mediates the alcoholysis and aminolysis of Mieso-epoxides in high enantioselectivities and furnishes valuable chiral 1,2-diol monoethers 2 and 1,2-amino alcohols 3 as products (PMB = para-methoxybenzyl).
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