STEREOCONTROLLED SYNTHESIS OF A TRANS-ANTI-TRANS TRICYCLE VIA A TRANSANNULAR DIELS-ALDER STRATEGY.

DOI: 10.1016/S0040-4039(00)82308-4

Source and publish data:

Tetrahedron Letters p. 6215 - 6218 (1988)

Update date:2022-08-05

Topics:

Authors:

Marinier, Anne

Deslongchamps, Pieere

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Article abstract of DOI:10.1016/S0040-4039(00)82308-4

Transannular Diels-Alder reaction of trans-cis-cis macrocyclic triene 20 yields trans-syn-cis tricycle 21 which is converted into trans-anti-trans tricycle 24 by epimerization at C₉ after appropriate functional group transformation.

Full text of DOI:10.1016/S0040-4039(00)82308-4

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