Preferred Conformation of C-Glycosides. 11. C-Sucrose: New Practical Synthesis, Structural Reassignment, and Solid-State and Solution Conformation of Its Octaacetate

DOI: 10.1021/jo00054a006

Source and publish data:

Journal of Organic Chemistry p. 304 - 306 (1993)

Update date:2022-07-30

Topics: Practical Synthesis C-glycosides Preferred conformation Solution conformation

Authors:

O'Leary, Daniel J.

Kishi, Yoshito

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00054a006

The stereochemistry of C-sucrose, previously reported from this laboratory, was revised as epi-C.2'-C-sucrose (5) from (1)H NOE measurements on octaacetates 2 and 6 and an X-ray analysis of 2.A new, stereospecific, and practical synthesis of C-sucrose (1)

Full text of DOI:10.1021/jo00054a006

Products guided by the article

Product name:(2S,3S,4S)-4-Benzyloxy-4-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-butane-1,2,3-triol

Cas No:145852-88-6

R&D Labs maybe for 145852-88-6

Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Nanjing Fubang Chemical Co.,Ltd

Contact:+86-25-83179199

Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China
Shandong Zhongcheng Barium Salt Co., Ltd

Contact:+86-15725732638

Address:No.29 baoxi road, hi-tech zone, zibo, shandong
MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN
Hangzhou Neway Chemicals Co., Ltd.

Contact:+86-571-85095566

Address:Room 803, Qinglian Bldg, No 139 Qingchun Road, Hangzhou, Zhejiang China

Relevant to this article

Lithiated aziridine reagents

Doi:10.1021/ja00057a073
(1993)
Design, Synthesis, and Neurochemical Evaluation of 5-(3-Alkyl-1,2,4-oxadiazol-5-yl)-1,4,5,6-tetrahydropyrimidines as M₁ Muscarinic Receptor Agonists

Doi:10.1021/jm00059a008
(1993)
Heterocycle formation through aza-annulation: A stereochemically controlled route to (±)-lupinine

Doi:10.1016/S0040-4039(00)60550-6
(1993)
Synthesis, Characterization and Properties of Novel Covalently Linked Binuclear Ruthenium(II) and Trinuclear Ruthenium(II)-Copper(I) Bipyridyl Complexes

Doi:10.1039/DT9930000817
(1993)
Doi:10.1021/ja01356a030
(1931)
Studies Directed Towards the Total Synthesis of Rhizoxin: Stereoselective Synthesis of C-12 to C-18 Segment

Doi:10.1016/S0040-4039(00)61659-3
(1993)

Article Doi