Preferred Conformation of C-Glycosides. 11. C-Sucrose: New Practical Synthesis, Structural Reassignment, and Solid-State and Solution Conformation of Its Octaacetate

DOI: 10.1021/jo00054a006

Source and publish data:

Journal of Organic Chemistry p. 304 - 306 (1993)

Update date:2022-07-30

Topics: Practical Synthesis C-glycosides Preferred conformation Solution conformation

Authors:

O'Leary, Daniel J.

Kishi, Yoshito

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Article abstract of DOI:10.1021/jo00054a006

The stereochemistry of C-sucrose, previously reported from this laboratory, was revised as epi-C.2'-C-sucrose (5) from (1)H NOE measurements on octaacetates 2 and 6 and an X-ray analysis of 2.A new, stereospecific, and practical synthesis of C-sucrose (1)

Full text of DOI:10.1021/jo00054a006

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