Preferred Conformation of C-Glycosides. 11. C-Sucrose: New Practical Synthesis, Structural Reassignment, and Solid-State and Solution Conformation of Its Octaacetate

Article abstract of DOI:10.1021/jo00054a006

The stereochemistry of C-sucrose, previously reported from this laboratory, was revised as epi-C.2'-C-sucrose (5) from (1)H NOE measurements on octaacetates 2 and 6 and an X-ray analysis of 2.A new, stereospecific, and practical synthesis of C-sucrose (1)