Journal of Organometallic Chemistry p. 375 - 388 (1992)
Update date:2022-08-04
Topics:
Dalcanale, E.
An, Z.
Battaglia, L. P.
Catellani, M.
Chiusoli, G. P.
The use of m-iodophenol as initiator in palladium-catalyzed norbornene-carbon monoxide oligomerization in the presence of potassium acetate unexpectedly leads to termination by double bond formation in spite of the limitations to β-H-anti elimination.The presence of endo products points to preliminary exo-to-endo isomerization through enolization.The X-ray structure of one stereoisomer (Ia) is given.
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