Tetrahedron Letters p. 7561 - 7564 (1992)
Update date:2022-08-03
Topics:
Takahashi, Takashi
Yamada, Haruo
Haino, Takeharu
Kido, Yoichi
Fukazawa, Yoshimasa
A dianion method for the construction of the macrocycles has been developed and applied to the synthesis of natural fragrance muscone.Conformational analysis of the macrocycle using MM2-Monte Carlo method was carried out to evaluate whether the rationally designed intermediate will readily cyclize.
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