Stereoselective Cyclomagnesiation of 1,6-Heptadienes Catalyzed by Zirconocenes: Effect of Substituents, Solvent and Magnesium Reagents

DOI: 10.1016/0040-4039(93)88032-E

Source and publish data:

Tetrahedron Letters p. 7735 - 7738 (1992)

Update date:2022-07-29

Topics:

Authors:

Wischmeyer, Ulrike

Knight, Kyle S.

Waymouth, Robert M.

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Article abstract of DOI:10.1016/0040-4039(93)88032-E

Zirconocene dichloride acts as a catalyst precursor for the stereoselective cyclomagnesiation of an array of substituted 1,6-heptadienes in the presence of butylmagnesium chloride to form trans 1,2-(bis)methylmagnesium substituted carbocycles.

Full text of DOI:10.1016/0040-4039(93)88032-E

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