
Tetrahedron p. 619 - 638 (1993)
Update date:2022-08-04
Topics:
Wang, Qian
Fan, Shi Yan
Wong, Henry N. C.
Li, Zhong
Fung, Bing M.
Twieg, Robert J.
Nguyen, Huu Tinh
Chiral liquid crystalline compounds 1-9 have been synthesized enantioselectively from monoterpenes. The optical purities of (S)-(-)- and (R)-(+)-perillalcohol (16, 27), (S)-(-)- and (R)-(+)-1-pentyl-4-hydroxymethyl-1-cyclohexene (33, 34) and (2S,5S)-2-pentyl-5-hydroxymethyl-1-cyclohexanone (53) have been determined by 1H NMR analysis using chiral shift reagents. The mesomorphic phases and transition temperatures of compounds 2,3,5,6,7,8 and 9 have been characterized.
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Doi:10.1016/S0040-4039(00)60547-6
(1993)Doi:10.1063/1.464187
(1993)Doi:10.1055/s-0033-1339376
(2013)Doi:10.1021/jo00061a009
(1993)Doi:10.1080/00397919708003049
(1997)Doi:10.1016/0304-5102(92)80208-X
(1992)