Z-selective formation of trisubstituted α,β-unsaturated nitrile by the Horner-Emmons reaction

DOI: 10.1016/S0040-4039(00)76763-3

Source and publish data:

Tetrahedron Letters p. 1581 - 1584 (1994)

Update date:2022-07-30

Topics:: Authors:

Takayanagi, Hisao

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Article abstract of DOI:10.1016/S0040-4039(00)76763-3

Conditions which allow the Horner-Emmons reaction of phosphononitrile to proceed Z-selectively were clarified. The generality and usefulness of the procedure were demonstrated by an application to a stereoselective synthesis of plaunotol (9).

Full text of DOI:10.1016/S0040-4039(00)76763-3

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Z-selective formation of trisubstituted α,β-unsaturated nitrile by the Horner-Emmons reaction

DOI: 10.1016/S0040-4039(00)76763-3

Source and publish data:

Authors:

Article abstract of DOI:10.1016/S0040-4039(00)76763-3

Full text of DOI:10.1016/S0040-4039(00)76763-3

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