Synthesis of five- and six-coordinate alkylidene complexes of the type Mo(CHR)(NAr)[OCMe(CF3)2]2Sx and their use as living ROMP initiators or wittig reagents

DOI: 10.1021/om00027a028

Source and publish data:

Organometallics p. 759 - 768 (1993)

Update date:2022-07-30

Topics:

Authors:

Fox, Harold H.

Lee, Jin-Kyu

Park, Lee Y.

Schrock, Richard R.

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Article abstract of DOI:10.1021/om00027a028

Addition of a slight excess of 4-methoxy-1-hexene to Mo(CHCMe₂Ph)(NAr)(OR_F6)₂ (1a) or Mo(CHCMe₃)(NAr)(OR_F6)₂ (1b) in pentane (OR_F6 = OCMe(CF₃)₂) yielded cry

Full text of DOI:10.1021/om00027a028

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Product name:Mo(N-2,6-Pr(i)2C₆H₃)2(CH₂Ph)2

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