A simple direct synthesis of an alkylaromatic palladacycle

DOI: 10.1016/0022-328X(92)85081-7

Source and publish data:

Journal of Organometallic Chemistry p. 369 - 373 (1992)

Update date:2022-07-29

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Authors:

Catellani, Marta

Chiusoli, Gian Paolo

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Article abstract of DOI:10.1016/0022-328X(92)85081-7

The first direct preparation of an alkylaromatic palladacycle is reported.It consists of the reaction of 1-bromo-3-cyanobenzene with norbornene and palladium(0) complexes in the presence of potassium phenoxide.

Full text of DOI:10.1016/0022-328X(92)85081-7

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Product name:CNC₆H₃(C₇H₁₀)^(2-)*Pd⁽²⁺⁾*P(C₆H₅)3=(CNC₆H₃(C₇H₁₀))Pd(P(C₆H₅)3)

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