Tetrahedron Letters p. 991 - 994 (1993)
Update date:2022-08-03
Topics:
Luengo
Konialian
Holt
The reactivity of rapamycin under mild Lewis-acid catalysis has been investigated. The molecule has been found to be extremely sensitive to basic reagents due to carboxylate elimination β to the C24 ketone. However, transformations normally eff
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