New Total Synthesis of (+)-N-Methylanisomycin by Anodic Cyclization of δ-Alkenylamine

DOI: 10.1016/S0040-4020(01)86320-1

Source and publish data:

Tetrahedron p. 2413 - 2426 (1993)

Update date:2022-08-06

Topics: Total synthesis Experimental terms

Authors:

Tokuda, Masao

Fujita, Hirotake

Miyamoto, Tohru

Suginome, Hiroshi

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Article abstract of DOI:10.1016/S0040-4020(01)86320-1

A chiral total synthesis of (+)-N-methylanisomycin (1a) from L-diethyl tartrate via 15 steps is reported.The key step in the synthesis was a regio- and stereoselective cyclization of (E)-δ-alkenylamine 12a or its (Z)-isomer 12b by anodic oxidation of thei

Full text of DOI:10.1016/S0040-4020(01)86320-1

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