Chemistry Letters p. 83 - 84 (1999)
Update date:2022-08-03
Topics:
Yamasaki, Yuki
Enomoto, Heiji
Yamasaki, Nakamichi
Nakahara, Masaru
CH2Cl2 (1 mole) mixed with NaOH (2 moles) was treated under hydrothermal conditions at 250 °C. The chlorinated methane was completely hydrolyzed to form methanol and the formate by the Cannizzaro reaction. The reactant and products were analyzed by 1H-, 2H-, and 13C-NMR. Solvent isotope effect on the transformation was also investigated. The hazardous and environmentally troublesome organic solvent was safely converted into the useful compounds.
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Doi:10.1021/acs.orglett.5b00663
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