A FACILE AND STEREOSELECTIVE SYNTHESIS OF α-METHYLENE-γ-BUTYROLACTONE BY MEANS OF CHROMIUM(II) REAGENT

DOI: 10.1246/cl.1985.481

Source and publish data:

Chemistry Letters p. 481 - 484 (1985)

Update date:2022-08-03

Topics:

Authors:

Okuda, Yasuhiro

Nakatsukasa, Shigeki

Oshima, Koichiro

Nozaki, Hitosi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1985.481

Treatment of ethyl α-(bromomethyl)acrylate with Cr(II) reagent derived from CrCl3 and LiAlH4 produces allylic chromium species which add to aldehydes efficiently to give α-methylene-γ-butyrolactones stereoselectively.

Full text of DOI:10.1246/cl.1985.481

Products guided by the article

Product name:cis-4-butyl-5-phenyl-4,5-dihydro-3-methylene-2(3H)-furanone

Cas No:148531-21-9

R&D Labs maybe for 148531-21-9

Xiamen Goodhealth Pharmchem Co., Ltd.

Contact:0086-592-2097683

Address:404R No.2 54# Minzu Rd., Xiamen, China
Geen Chemical Technology Co., Ltd

Contact:86-769-21660847

Address:1408, Yingfeng Commercial Center, Nancheng District
Shanghai FWD Chemicals ltd

website:http://www.fwdchem.com

Contact:86-21-54450828

Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai
EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Shanghai Balmxy Pharmaceutical Co., Ltd

Contact:0086-21-24206007

Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China

Relevant to this article

X-ray diffraction and theoretical studies for the quantitative assessment of intermolecular arene-perfluoroarene stacking interactions

Doi:10.1002/chem.200501248
(2006)
Synthesis, and spectral and X-ray structural studies of a novel delocalised triphosphazene (CF3)2P=N=P(CF3)2=N=PPh3 and the triosmium cluster complex Os3(CO)11<(CF3)2P=N=P(CF3)2=N=PPh3>

Doi:10.1016/0022-328X(93)80088-S
(1993)
Synthesis, hypoglycemic activity and molecular modeling studies of pyrazole-3-carbohydrazides designed by a CoMFA model

Doi:10.1016/j.ejmech.2013.07.054
(2013)
Stereospecific Synthesis of 3-Oxo-α-bourbonene and the Cisoid Isomer for Structural Determination of the Toxic Component of Lansium domesticum

Doi:10.1246/bcsj.61.2672
(1988)
Natural product chemistry. Part 153. Synthesis and possible anticancer activity of 8-nitronoracronycine

Doi:10.1002/jhet.5570290538
(1992)
Novel N-methylsulfonamide and retro-N-methylsulfonamide derivatives as 17β-hydroxysteroid dehydrogenase type 2 (17β-HSD2) inhibitors with good ADME-related physicochemical parameters

Doi:10.1016/j.ejmech.2013.08.026
(2013)

Article Doi