Reaction of Dodecacarbonyltriruthenium with 7-Oxabicyclohept-5-en-2-yl Derivatives: Synthesis of(μ3-η2-Benzyne)-nonacarbonyldihydridotriruthenium and Derivatives

DOI: 10.1039/c39910001334

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1334 - 1335 (1991)

Update date:2022-08-04

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Authors:

Bonfantini, Edia

Vogel, Pierre

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Article abstract of DOI:10.1039/c39910001334

The thermal reaction of with 7-oxabicyclo<2.2.1>hept-5-en-2-yl derivatives gave the corresponding hept-5-yn-2-yl)> clusters; treatment of the complex derived from 7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl benzoate with (CH3)3SiOSO2CF3 gave a mixture of and .

Full text of DOI:10.1039/c39910001334

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