Journal of the Chemical Society. Chemical communications p. 615 - 617 (1992)
Update date:2022-08-03
Topics:
Lin, Shie-Hsiung
Peng, Shie-Ming
Liu, Rai-Shung
The syntheses of compounds of the type CpMo(CO)2<η3-anti-1-CH2CH(OH)R-syn-3-R'CH2-C3H3> are described; their reactions with excess nitrosonium tetrafluoroborate produce 3-(1'-R'CH2CH=CH)-5-R-isoxazole, which involves a remarkable nitrosyl insertion into the ?-allyl ligand as the key step.
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