Tetrahedron Letters p. 1811 - 1814 (1993)
Update date:2022-07-30
Topics:
Galan, Emilio R.
Chamizo, Maria J.
Serrano, Jose A.
Thermal and catalytic Diels-Alder reactions of 1 with 2,3-dimethyl-1,3-butadiene gave 4-formyl-5-glycocyclobexenes 2 and 3. Absolute configurations at the new chiral centers in the adducts are based on polarimetric correlation with known compounds. On reduction and acid treatment, the adducts 2 and 3 were converted into 6-oxabicyclo[3.2.1]octanes 13 and 15.
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(2015)
