
Journal of Organometallic Chemistry p. 67 - 72 (1993)
Update date:2022-08-04
Topics:
Archibald, R. Scott
Winkel, Yvar van den
Powell, Douglas R.
West, Robert
Synthesis of the new disilene, E/Z-IsMesSi=SiIsMes (1) is reported; the isomer Is2Si=SiMes2 (2) was obtained by photolysis of a mixture of Mes2Si(SiMe3)2 (3) and Is2Si(SiMe3)2 (5).Isomerization of 1 <*> 2 does not take place up to 80 deg C.X-Ray crystal s
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