Linear 2,2-diaryl-substituted trisilanes: structure and photolysis to disilenes

DOI: 10.1016/0022-328X(93)80035-A

Source and publish data:

Journal of Organometallic Chemistry p. 67 - 72 (1993)

Update date:2022-08-04

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Authors:

Archibald, R. Scott

Winkel, Yvar van den

Powell, Douglas R.

West, Robert

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Article abstract of DOI:10.1016/0022-328X(93)80035-A

Synthesis of the new disilene, E/Z-IsMesSi=SiIsMes (1) is reported; the isomer Is2Si=SiMes2 (2) was obtained by photolysis of a mixture of Mes2Si(SiMe3)2 (3) and Is2Si(SiMe3)2 (5).Isomerization of 1 <*> 2 does not take place up to 80 deg C.X-Ray crystal s

Full text of DOI:10.1016/0022-328X(93)80035-A

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