Fluxional Ligand Migrations in Triosmium Clusters containing 2-Pyridylphosphines

DOI: 10.1039/c39930000844

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 844 - 846 (1993)

Update date:2022-08-04

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Authors:

Deeming, Antony J.

Smith, Martin B.

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Article abstract of DOI:10.1039/c39930000844

The cluster (L = Ph2PC5H4N) (X-ray structure reported), containing the diaxially coordinated 2-pyridyldiphenylphosphine bridge, undergoes rapid transfer of the pyridine between two metal atoms while the phosphorus atom remains firmly coor

Full text of DOI:10.1039/c39930000844

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