Journal of Organic Chemistry p. 4646 - 4655 (1993)
Update date:2022-08-04
Topics:
Padwa, Albert
Dean, Dennis C.
Fairfax, David J.
Xu, Simon L.
The rhodium(II) carboxylate catalyzed decomposition of several α-diazo esters and amides has been studied.A series of 5-keto-1-diazo acetates were prepared by acylation of α-hydroxy ketones using the (p-toluenesulfonyl)hydrazone of glyxylic acid chloride.
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