Asymmetric Selenomethoxylation of Olefins Involving a Chiral C2 Symmetrical Electrophilic Organoselenium Reagent

DOI: 10.1021/jo00066a010

Source and publish data:

Journal of Organic Chemistry p. 3619 - 3621 (1993)

Update date:2022-08-04

Topics:

Authors:

Deziel, Robert

Goulet, Sylvie

Grenier, Louis

Bordeleau, Josee

Bernier, Julie

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Article abstract of DOI:10.1021/jo00066a010

A new chiral C2 symmetrical organoselenium reagent has been synthesized; this compound, in the presence of methanol, reacts with high facial selectivity with olefins to afford the anti selenomethoxylated adducts in very good yields.

Full text of DOI:10.1021/jo00066a010

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