
Journal of Organic Chemistry p. 5377 - 5385 (1993)
Update date:2022-09-26
Topics: Method Sigmatropic rearrangement Preparing
Wang, Xiaoheng
Ni, Zhijie
Lu, Xiujing
Hollis, Andrea
Banks, Harold
et al.
Several β-sulfoxy-substituted acetylenic carbinols were prepared by the addition of thiyl radicals and oxygen to conjugated enynes.The products obtained are derived from thiyl radical attack at the olefinic bond to generate a propargylic radical.Capture o
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