Self-Assembly of a Macrocyclic Dinuclear Pd(II)-Phosphine Complex

DOI: 10.1246/bcsj.66.1837

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1837 - 1839 (1993)

Update date:2022-07-31

Topics:

Authors:

Fujita, Makoto

Yazaki, Jun

Kuramochi, Tadao

Ogura, Katsuyuki

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Article abstract of DOI:10.1246/bcsj.66.1837

Reaction of a diphosphine ligand, bis<4-<2-(diphenylphosphino)ethyl>phenyl>ether (1) with Na2PdCl4 gave a macrocyclic dinuclear complex 2 (2) in a 58percent isolated yield.The formation of 2 appears to result from a spontaneous self-assembly process under thermodynamic control, and thus, no special technique such as a high-dilution method was needed.

Full text of DOI:10.1246/bcsj.66.1837

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