Journal of Organic Chemistry p. 4539 - 4546 (1993)
Update date:2022-08-02
Topics: Regioselectivity Column chromatography Yield Catalyst Stereochemistry Olefin Conformation Heteroatom TLC (thin-layer chromatography) Oxime X-ray crystallography Cycloaddition Activation Energy Reaction Optimization Solvent Effect Mechanistic study NMR spectroscopy (Nuclear Magnetic Resonance) DFT Calculations (Density Functional Theory)
Hassner, Alfred
Maurya, Rakesh
Friedman, Oded
Gottlieb, Hugo E.
Padwa, Albert
Austin, David
Thermal intramolecular oxime olefin cycloaddition of α-allylamino aldoximes and ketoximes 4 led stereospecifically to formation of oxadiazabicyclo<3.3.0>octanes 6.The presence of heteroatoms in these bicyclic fused 5-membered rings permits for the first t
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