On the Conformation of Fused Five-Membered Heterocyclic Rings Derived from the Intramolecular Oxime Olefin Cycloaddition Reaction

DOI: 10.1021/jo00069a011

Source and publish data:

Journal of Organic Chemistry p. 4539 - 4546 (1993)

Update date:2022-08-02

Topics: Regioselectivity Column chromatography Yield Catalyst Stereochemistry Olefin Conformation Heteroatom TLC (thin-layer chromatography) Oxime X-ray crystallography Cycloaddition Activation Energy Reaction Optimization Solvent Effect Mechanistic study NMR spectroscopy (Nuclear Magnetic Resonance) DFT Calculations (Density Functional Theory)

Authors:

Hassner, Alfred

Maurya, Rakesh

Friedman, Oded

Gottlieb, Hugo E.

Padwa, Albert

Austin, David

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00069a011

Thermal intramolecular oxime olefin cycloaddition of α-allylamino aldoximes and ketoximes 4 led stereospecifically to formation of oxadiazabicyclo<3.3.0>octanes 6.The presence of heteroatoms in these bicyclic fused 5-membered rings permits for the first t

Full text of DOI:10.1021/jo00069a011

Products guided by the article

Product name:N-(2-trans-Butenyl)-N-phenyl-1-amino-2-acetophenone

Cas No:150630-83-4

R&D Labs maybe for 150630-83-4

Qida Chemical Co., Ltd.(expird)

Contact:+86-25-8776 0031

Address:3-2001 Jiaye Int'l Town, 158 Lushan Road,Nanjing, 210019, China
Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Jiangxi Global Natural Spice Co., Ltd.

website:https://www.jxhqxl.com/

Contact:+86-796-8106598

Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
Taizhou Chemedir Biopharm-tech Co., Ltd

Contact:+86 523 86200218

Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China

Relevant to this article

Synthesis of sialyl Lewis X mimetics and related structures using the glycosyl phosphite methodology and evaluation of E-selectin inhibition

Doi:10.1021/ja952265x
(1996)
Excellent chiral introduction by diene iron-tricarbonyl moiety. III: Asymmetric synthesis of hydroxyethylidene dipeptide isostere using a diastereoselective 1,2-nucleophilic addition of organocerium reagents into a 1-azatriene Fe(CO)₃ complex

Doi:10.1248/cpb.44.948
(1996)
Synthesis, Spectral, and Coordination Properties of Halogen-Substituted Tetraarylporphyrins

Doi:10.1134/S1070363219030150
(2019)
Super-microporous silica-supported platinum catalyst for highly regioselective hydrosilylation

Doi:10.1016/j.catcom.2017.04.015
(2017)
Highly stereoselective synthesis of vinyl and ethynylcyclopropane 1,1-dicarboxylic esters via semi-stabilized telluronium ylides

Doi:10.1016/0040-4020(96)00427-9
(1996)
Rh-catalyzed linear hydroformylation of styrene

Doi:10.1039/c2dt31738a
(2013)

Article Doi