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Reactions of [Au(acac)PPh3] with diphosphine derivatives: Different coordination modes of gold to the ligand systems. X-ray structure of [SPPh2C(AuPPh3)2PPh2CH(AuPPh 3)COOMe]ClO4

DOI: 10.1021/om00034a034

Source and publish data:

Organometallics p. 3984 - 3991 (1993)

Update date:2022-09-26

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Authors:

Gimeno, M. ConcepciónGimeno, M. Concepción

Laguna, AntonioLaguna, Antonio

Laguna, MarianoLaguna, Mariano

Sanmartín, FedericoSanmartín, Federico

Jones, Peter G.Jones, Peter G.

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Article abstract of DOI:10.1021/om00034a034

Reactions of various diphosphine ligands with [Au(acac)PPh3] (acac = acetylacetonate) are reported. In all cases the ligand is deprotonated by displacement of acac as acetylacetone and subsequently coordinates the gold or the AuPPh3<

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Full text of DOI:10.1021/om00034a034

Products guided by the article

Product name:CH(P(C6H5)2(S))(P(C6H5)2(CH3))(AuP(C6H5)3)(1+)*ClO4(1-)={CH(P(C6H5)2(S))(P(C6H5)2(CH3))(AuP(C6H5)3)}ClO4

Cas No:150675-37-9

150675-37-9

R&D Labs maybe for 150675-37-9

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