Reactions of [Au(acac)PPh3] with diphosphine derivatives: Different coordination modes of gold to the ligand systems. X-ray structure of [SPPh2C(AuPPh3)2PPh2CH(AuPPh 3)COOMe]ClO4

DOI: 10.1021/om00034a034

Source and publish data:

Organometallics p. 3984 - 3991 (1993)

Update date:2022-09-26

Topics:

Authors:

Gimeno, M. Concepción

Laguna, Antonio

Laguna, Mariano

Sanmartín, Federico

Jones, Peter G.

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Article abstract of DOI:10.1021/om00034a034

Reactions of various diphosphine ligands with [Au(acac)PPh₃] (acac = acetylacetonate) are reported. In all cases the ligand is deprotonated by displacement of acac as acetylacetone and subsequently coordinates the gold or the AuPPh₃<

Full text of DOI:10.1021/om00034a034

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Product name:CH(P(C₆H₅)2(S))(P(C₆H₅)2(CH₃))(AuP(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-)={CH(P(C₆H₅)2(S))(P(C₆H₅)2(CH₃))(AuP(C₆H₅)3)}ClO₄

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