Silica gel catalysed rearrangement of α-epoxyketones to 1,2-diketones

Article abstract of DOI:10.1080/00397919308011247

A convenient and simple method for the preparation of diphenylpropane-1,2-diones is described. The process involves rearrangement of α-epoxyketones on silica gel; an unusual migration of a proton instead of the more common benzoyl migration.

Full text of DOI:10.1080/00397919308011247

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Silica Gel Catalysed
Rearrangement of α-
Epoxyketones to 1,2-Diketones
T. Bharati Rao a & J. Madhusudana Rao a
a Regional Research Laboratory (CSIR) , Trivandrum,
695019, India
Published online: 23 Sep 2006.
To cite this article: T. Bharati Rao & J. Madhusudana Rao (1993) Silica Gel Catalysed
Rearrangement of α-Epoxyketones to 1,2-Diketones, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 23:11,
1527-1533, DOI: 10.1080/00397919308011247
To link to this article: http://dx.doi.org/10.1080/00397919308011247
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