Journal of the American Chemical Society p. 11990 - 11998 (1994)
Update date:2022-08-03
Topics:
Wiberg, Kenneth B.
McMurdie, Neil
The ionization of 1-bicyclo[1.1.1]pentyl halides was shown to initially form the 1,3-bridged bicyclo[1.1.1]pentyl-l cation. It appears to be a transition state that leads to the bicyclo[1.1.0]butyl-1-carbinyl cation which can be trapped with azide ion and
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