Chemical Communications p. 1169 - 1170 (1996)
Update date:2022-08-05
Topics:
Constable, Edwin C.
Dunne, Simon J.
Rees, David G. F.
Schmitt, Chantal X.
The metallated complex [Ru(tbp)(tpy)][PF6] [Htbp = 6-(2-thienyl)-2,2′-bipyridine, tpy = 2,2′:6′,2″-terpyridine] is converted to the non-metallated species [Ru(Htbp)(tpy)][PF6] containing an N,N,S-bonded Htbp ligand upon treatment with acid; this process is reversed upon reaction of [Ru(Htbp)(tpy)][PF6] with aqueous sodium hydroxide solution.
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