Synthesis of Bis(phosphinomethyl)amines via Bis(hydroxymethyl)phosphonium Salts. Isolation of 9,9-Bis(hydroxymethyl)-9-phosphoniabicyclononane Hydrogensulfate and Chloride Salts, and the Crystal Structures of (1+)Cl(1-) and <(C6H11)2P

DOI: 10.1039/DT9930002563

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Journal of the Chemical Society, Dalton Transactions p. 2563 - 2568 (1993)

Update date:2022-08-03

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Authors:

Fawcett, John

Hoye, Peter A. T.

Kemmitt, Raymond D. W.

Law, David J.

Russell, David R.

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Article abstract of DOI:10.1039/DT9930002563

Phosphines of the type PR2H reacted readily with formaldehyde in the presence of acid to afford high yields of bis(hydroxymethyl)phosphonium salts (1+)X(1-), (1+)X(1-), <*>, and <*> (X = Cl or HSO4).Treatment of the mixed

Full text of DOI:10.1039/DT9930002563

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